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I got this solution from
http://www.experts-exchange.com/

Add the following:
#
WinXP on HDD 2
title Windows XP on hard disk 2
map (hd0) (hd2)
map (hd2) (hd0)
rootnoverify (hd2,0)

How do I add another Windows XP SATA Hard Drive to this Grub menu, on a USB Stick?:

timeout 30
default 0
#
WinXP on HDD
title Windows XP on hard disk
map (hd0) (hd1)
map (hd1) (hd0)...